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Germanium doping of aluminum-containing cubic group III-nitride heterostructures / von Michael Deppe. Paderborn, 2020
Inhalt
Contents
1 Introduction
2 Fundamentals
2.1 Properties of group III nitrides
2.2 Doping
2.2.1 General
2.2.2 Temperature dependence of carrier concentration
2.2.3 Effects at high doping levels
2.2.4 Doping of group III nitrides
2.3 Epitaxy
2.3.1 Epitaxy methods
2.3.2 Molecular beam epitaxy
Generation of molecular beams
Growth process
2.3.3 Antiphase domains
2.3.4 Growth monitoring via reflection high-energy electron diffraction
2.4 Multiple quantum wells, superlattices and intersubband absorption
2.4.1 Doping of quantum wells
3 Experimental techniques
3.1 Growth of cubic nitrides
3.1.1 Setup of the molecular beam epitaxy system
3.1.2 Substrate preparation
3.1.3 Growth of c-GaN
3.1.4 Growth of c-AlN
3.1.5 Growth of c-Al(x)Ga(1-x)N
3.2 Characterization methods
3.2.1 High-resolution x-ray diffraction
3.2.2 Atomic force microscopy
3.2.3 Secondary ion mass spectrometry
3.2.4 Hall effect measurements
3.2.5 Capacitance-voltage spectroscopy
3.2.6 Photoluminescence spectroscopy
Fundamentals of photoluminescence spectroscopy
Experimental setup
3.3 Intersubband absorption
3.3.1 Sample preparation
3.3.2 Measurement setup and procedure
4 Results and discussion
4.1 Influence of layer thickness on structural properties
4.2 Calibration of the time-of-flight secondary ion mass spectrometry Ge-signal
4.3 Ge- and Si-doping of c-GaN
4.3.1 Time-of-flight secondary ion mass spectrometry depth profiles
4.3.2 Structural properties
4.3.3 Electrical properties
4.3.4 Optical properties
4.3.5 Limit of doping
4.3.6 Discussion
4.4 Ge-doping of c-Al(x)Ga(1-x)N
4.4.1 Time-of-flight secondary ion mass spectrometry depth profiles
4.4.2 Structural properties
RHEED patterns
EDX analysis
HRXRD measurements
AFM measurements
4.4.3 Electrical properties
4.4.4 Optical properties
4.4.5 Conclusion
4.5 Reduction of growth rates at high doping levels
4.6 Ge-doping of GaN/AlN superlattices
4.6.1 nextnano3 simulations
4.6.2 Quantum well doping level
4.6.3 Structural properties
4.6.4 Photoluminescence spectroscopy
4.6.5 Intersubband absorption measurements
4.6.6 Impact of layer quality and substrate properties on absorption
5 Summary and outlook
Bibliography
Appendix
A Appendix A
A.1 Calibration of substrate temperature
A.2 Deep defect level in 0 – persistent photoconductivity measurements
B Appendix B - supporting figures
C Appendix C - nextnano3 input file
D Appendix D - list of samples
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