Development of cyclometalated iron complexes as sustainable photosensitizers / vorgelegt von Jakob Steube ; Jun.-Prof. Dr. Hans-Georg Steinrück: Vorsitz, Prof. Dr. Matthias Bauer: Erstgutachter, Prof. Dr. Thomas Werner: Zweitgutachter, PD Dr. Hans Egold: Drittprüfer. Paderborn, 2023
Inhalt
- Eidesstattliche Erklärung
- Abstract
- Kurzzusammenfassung
- Danksagungen
- List of Publications
- Cooperations and Tools
- Index of Abbreviations
- Introduction
- Objectives and motivation
- Results and Discussion
- Conclusion
- Experimental Part
- General work techniques
- Analytical and spectroscopic methods
- Column chromatography
- NMR spectroscopy
- IR spectroscopy
- Mass spectrometry
- Elemental analysis
- Single-crystal X-ray diffraction
- Cyclic voltammetry
- UV-Vis spectroscopy
- Steady-state emission spectroscopy
- Time-Correlated Single Photon Counting
- Synthesis
- Ligand synthesis
- Synthesis of 3-(Dimethylamino)-1-(2-phenyl)-2-propen-1-one (vk.one)
- Synthesis of 3-(Dimethylamino)-1-(2-pyridyl)-2-propen-1-one (vk.two)
- Synthesis of 6-phenyl-2,2'-bipyridine (pbpy)
- Synthesis of 1-(2-oxo-2-(2-pyridinyl)ethyl)pyridinium iodide (krr)
- Synthesis of N,N-dimethyl-3-oxo-3-phenylpropan-1-aminium chloride (mann)
- Synthesis of 6-(2-bromophenyl)-2,2'-bipyridine (Brpbpy)
- Synthesis of 4,4'-bis(trifluoromethyl)-2,2'-bipyridine
- Synthesis of 6-chloro-4,4'-bis(trifluoromethyl)-2,2'-bipyridine (bpy.CF3Cl)
- Synthesis of (2,4-difluoro-3-(trifluoromethyl)phenyl)boronic acid
- Synthesis of bis(imidazolyl)benzenes (core.H,Br,Me,tBu,OMe,CF3)
- Synthesis of CCC-proligands (lig.H,Br,Me,tBu,OMe,CF3)
- Complex synthesis
- Synthesis of [Fe(pbpy)2] Fepbpy via transmetalation
- Synthesis of [Fe(pbpy)2] Fepbpy via CH-activation
- Synthesis of CCC-complexes
- Synthesis of [Fe(ImPH)2](PF6) (feimp.H)
- Synthesis of [Fe(ImPBr)2](PF6) feimp.Br
- Synthesis of [Fe(ImPMe)2](PF6) feimp.Me
- Synthesis of [Fe(ImPtBu)2](PF6) feimp.tBu
- Synthesis of [Fe(ImPOMe)2](PF6) feimp.OMe
- Synthesis of [Fe(ImPCF3)2](PF6) feimp.CF3
- Synthesis of [Fe(ImPOCF3)2](PF6) feimp.OCF3
- Synthesis of [Fe(ImPCN)2](PF6) feimp.CN
- Catalysis
- List of Figures
- List of Schemes
- List of Tables
- Appendix
- Spectra
- Crystal Data
- Supplementary Information of the publications