Water under metal-organic framework confinement: systematic studies of the water sorption behavior and water interactions in one-dimensional pores / Marvin Kloß ; [First Reviewer: Prof. Dr. Michael Tiemann, Second Reviewer: Prof. Dr. Sebastian Henke]. Paderborn, 2024
Inhalt
- Abstract
- Kurzfassung
- Introduction
- Metal-organic Frameworks
- Structure and Properties of CPO-27
- Properties of CPO-27 and Its Interactions with Small Molecules
- Reticular Synthesis
- Water Sorption of Porous Materials
- Water Sorption Isotherms
- Porous Carbons
- Porous Silica-based Compounds
- Metal-Organic Frameworks
- Water Sorption Behavior of CPO-27-type Frameworks
- Chemistry of Water in Confined Spaces
- Motivation
- Influence of the Metal Center on the Properties of CPO-27-M
- Water Sorption Behavior of Pore Engineered CPO-27-Ni
- Hydration Behavior of CPO-27-M
- Impact of the Metal Center on the Hydration of CPO-27-M (Cu, Zn)
- Water in the Micropores of CPO-27 Metal-Organic Frameworks
- Water Sorption Behavior of Pore Engineered CPO-27-Ni
- Summary and Outlook
- Bibliography