Base Metal Iron(II)-Cobalt(III) Dyads for Photocatalytic Hydrogen Evolution / vorgelegt von Marina Huber-Gedert ; [Prof. Dr. Matthias Bauer (Erstgutachter), Privatdozent Dr. Hans Egold (Zweitgutachter)]. Paderborn, 2022
Inhalt
- Abstract
- Kurzzusammenfassung
- Danksagung
- List of Beamtimes
- List of Publications
- Abbreviations
- Investigated Ligands
- Investigated Complexes
- Introduction
- Background
- Climate Change and Global Warming
- Hydrogen Production
- Homogenous Photocatalytic Water Splitting
- Photosensitizer
- Photophysics of iron and ruthenium d6 complexes
- Strategies for MLCT lifetime elongation in iron d6 complexes
- Catalyst
- Dyads
- Hybrid dyads with Ru and Ir photosensitizers
- Noble-metal-free photosensitizers attached to cobaloxime
- Objectives
- Ligand Design
- Iron Complexes
- Multimetal Complexes
- Photocatalytic Hydrogen Production
- Summary and Outlook
- Experimental Part
- General laboratory information
- Analytic and spectroscopic methods
- Ligand synthesis
- Complex synthesis
- Bibliography
- Spectra
- Crystallographic data
- Computational chemistry
- Cyclic voltammograms
- List of Figures
- List of Tables